{"id":3800,"date":"2022-07-28T13:03:28","date_gmt":"2022-07-28T04:03:28","guid":{"rendered":"http:\/\/133.30.28.157\/?post_type=achievement&#038;p=3800"},"modified":"2023-09-01T11:54:52","modified_gmt":"2023-09-01T02:54:52","slug":"%e3%82%a8%e3%83%bc%e3%83%86%e3%83%ab%e5%88%86%e5%ad%90%e3%81%af%e3%81%99%e3%81%bf%e3%81%a3%e3%81%93%e3%81%8c%e3%81%8a%e5%a5%bd%e3%81%8d%ef%bc%9f%ef%bc%8d%e9%9b%bb%e5%a0%b4%e3%83%bb%e7%a3%81%e5%a0%b4","status":"publish","type":"achievement","link":"http:\/\/133.30.28.157\/achievement\/2022_07_28_3800.html","title":{"rendered":"\u30a8\u30fc\u30c6\u30eb\u5206\u5b50\u306f\u3059\u307f\u3063\u3053\u304c\u304a\u597d\u304d\uff1f\uff0d\u96fb\u5834\u30fb\u78c1\u5834\u30fb\u5149\u3067\u30ca\u30ce\u7a7a\u9593\u306b\u304a\u3051\u308b\u4e8c\u5143\u7cfb\u6eb6\u5a92\u306e\u4e0d\u5747\u4e00\u5316\u3092\u77e5\u308b\uff0d"},"content":{"rendered":"<h4>\u6982\u8981<\/h4>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" src=\"http:\/\/133.30.28.157\/wp-content\/uploads\/2022\/07\/samune-226x300.jpg\" alt=\"\" width=\"226\" height=\"300\" class=\"size-medium wp-image-3817 alignright\" \/>\u3000\u795e\u6238\u5927\u5b66\u5927\u5b66\u9662\u5de5\u5b66\u7814\u7a76\u79d1\u5fdc\u7528\u5316\u5b66\u5c02\u653b\u306e\u5927\u5b66\u9662\u751f \u9234\u6728\u826f\u5c06\u3001\u570b\u65b9\u4f38\u4eae (\u73fe\u30fb\u5bcc\u5c71\u770c\u7523\u696d\u6280\u8853\u7814\u7a76\u958b\u767a\u30bb\u30f3\u30bf\u30fc) \u3089\u306f\u3001\u30ca\u30ce\u7a7a\u9593\u306b\u5b58\u5728\u3059\u308b\u96fb\u6c60\u7528\u96fb\u89e3\u6db2\u306b\u7528\u3044\u3089\u308c\u308b\u4e8c\u5143\u7cfb\u975e\u6c34\u6eb6\u5a92\u306b\u304a\u3044\u3066\u6eb6\u5a92\u304c\u4e0d\u5747\u5316\u3092\u304a\u3053\u3059\u3053\u3068\u3001\u307e\u305f\u3001\u7279\u306b\u30a8\u30fc\u30c6\u30eb\u9396\u3092\u6709\u3059\u308b\u30b0\u30e9\u30a4\u30e0\u7cfb\u5206\u5b50\u304c\u56fa\u4f53\u8868\u9762\u306b\u51dd\u96c6\u3057\u3001\u7c98\u6027\u3092\u8457\u3057\u304f\u5897\u5927\u3055\u305b\u308b\u3053\u3068\u3092\u898b\u3044\u51fa\u3057\u307e\u3057\u305f\u3002<\/p>\n<p>\u3000\u672c\u7814\u7a76\u306f\u3001\u795e\u6238\u5927\u5b66\u5927\u5b66\u9662\u5de5\u5b66\u7814\u7a76\u79d1\u5fdc\u7528\u5316\u5b66\u5c02\u653b\u306e\u6c34\u7551\u7a63\u6559\u6388\u3068\u6771\u5317\u5927\u5b66\u672a\u6765\u79d1\u5b66\u6280\u8853\u5171\u540c\u7814\u7a76\u30bb\u30f3\u30bf\u30fc (NICHe) \u306e\u6817\u539f\u548c\u679d\u6559\u6388\u306e\u4ed6\u3001\u5317\u6d77\u9053\u5927\u5b66\u3001\u516c\u7acb\u5c0f\u677e\u5927\u5b66\u3001\u30e4\u30b2\u30a6\u30a9\u5927\u5b66\u304b\u3089\u306a\u308b\u7814\u7a76\u30b0\u30eb\u30fc\u30d7\u306b\u3088\u308a\u884c\u308f\u308c\u307e\u3057\u305f\u3002<\/p>\n<p>\u3000\u3053\u306e\u7814\u7a76\u6210\u679c\u306f\u30017\u670812\u65e5\u306b\u7c73\u56fd\u5316\u5b66\u4f1a (American Chemical Society) \u304c\u767a\u884c\u3059\u308b<i>Journal of Physical Chemistry C<\/i><span>\u00a0<\/span>\u306b\u30aa\u30f3\u30e9\u30a4\u30f3\u63b2\u8f09\u3055\u308c\u308b\u3068\u3068\u3082\u306bSupplementary Cover\u3068\u3057\u3066\u63a1\u629e\u3055\u308c7\u670821\u65e5\u306b\u516c\u958b\u3055\u308c\u307e\u3057\u305f\u3002<\/p>\n<h4>\u30dd\u30a4\u30f3\u30c8<\/h4>\n<p>\u30fb\u56fa\u4f53\u8868\u9762\u306b\u3088\u308a\u5f62\u6210\u3055\u308c\u305f\u30ca\u30ce\u7a7a\u9593\u306b\u304a\u3051\u308b\u4e8c\u5143\u7cfb\u975e\u6c34\u6eb6\u5a92\u306e\u4e0d\u5747\u5316\u73fe\u8c61\u3092\u30a4\u30aa\u30f3\u4f1d\u5c0e\u6e2c\u5b9a\u30fb\u305a\u308a\u7c98\u6027\u6e2c\u5b9a\u306b\u3088\u308a\u898b\u3044\u3060\u3057\u305f\u3002<\/p>\n<p>\u30fb\u96fb\u89e3\u8cea\u6fc3\u5ea6\u3092\u4e0a\u3052\u308b\u3053\u3068\u306b\u3088\u3063\u3066\u3001\u4e0d\u5747\u5316\u306f\u6291\u5236\u3055\u308c\u3001\u30a4\u30aa\u30f3\u79fb\u52d5\u304c\u30b9\u30e0\u30fc\u30ba\u306b\u304a\u3053\u308b\u3053\u3068\u304c\u898b\u3044\u51fa\u3055\u308c\u305f\u3002<\/p>\n<p>\u30fb\u5f97\u3089\u308c\u305f\u7d50\u679c\u306f\u96fb\u6c60\u6750\u6599\u5185\u306e\u30ca\u30ce\u7d30\u5b54\u306b\u304a\u3051\u308b\u6db2\u4f53\u306e\u69cb\u9020\u3084\u6d41\u52d5\u3001\u30a4\u30aa\u30f3\u306e\u79fb\u52d5\u306b\u5bfe\u3057\u3066\u56fa\u76f8\u306e\u8868\u9762\u7269\u6027\u304c\u5927\u304d\u306a\u5f71\u97ff\u3092\u4e0e\u3048\u308b\u3053\u3068\u3092\u793a\u3057\u3066\u304a\u308a\u3001\u96fb\u6c60\u6750\u6599\u306e\u958b\u767a\u306b\u304a\u3044\u3066\u8868\u9762\u5236\u5fa1\u304c\u91cd\u8981\u306a\u8981\u7d20\u6280\u8853\u3068\u306a\u308b\u3053\u3068\u3092\u754c\u9762\u96fb\u6c17\u5316\u5b66\u306e\u7acb\u5834\u304b\u3089\u793a\u3057\u305f\u3002<\/p>\n<h4>\u7814\u7a76\u306e\u80cc\u666f<\/h4>\n<p><span>\u3000\u30ea\u30c1\u30a6\u30e0\u30a4\u30aa\u30f3\u96fb\u6c60\u306f\uff14V\u3092\u8d8a\u3048\u308b\u9ad8\u3044\u96fb\u5727\u4e0b\u3067\u52d5\u4f5c\u3057\u307e\u3059\u3002\u3053\u306e\u3088\u3046\u306a\u9ad8\u3044\u96fb\u5727\u3067\u52d5\u4f5c\u3055\u305b\u308b\u306b\u306f\u305d\u306e\u96fb\u5727\u3067\u5206\u89e3\u3055\u308c\u306a\u3044\u3088\u3046\u3001\u6709\u6a5f\u6eb6\u5a92\u304c\u7528\u3044\u3089\u308c\u307e\u3059\u3002\u4e00\u822c\u7684\u306b\u30ea\u30c1\u30a6\u30e0\u96fb\u89e3\u8cea\u3092\u826f\u304f\u6eb6\u304b\u3059\u6eb6\u5a92\u306f\u7c98\u6027\u304c\u9ad8\u3044\u305f\u3081\u3001\u53cd\u5fdc\u3092\u4fc3\u9032\u3059\u308b\u305f\u3081\u4f4e\u7c98\u6027\u6eb6\u5a92\u3092\u6df7\u5408\u3057\u3066\u7528\u3044\u3089\u308c\u307e\u3059\u3002\u4e00\u65b9\u3001\u9ad8\u51fa\u529b\u306a\u96fb\u6c60\u3092\u5b9f\u73fe\u3059\u308b\u306b\u306f\u96fb\u6d41\u3092\u5927\u304d\u304f\u53d6\u308a\u51fa\u305b\u308b\u96fb\u6975\u6750\u6599\u3084\u9694\u819c (\u30bb\u30d1\u30ec\u30fc\u30bf\u30fc) \u304c\u5fc5\u8981\u3067\u3042\u308a\u3001\u305d\u306e\u305f\u3081\u306b\u5fae\u7d30\u306a\u7c92\u5b50\u304b\u3089\u306a\u308b\u8868\u9762\u7a4d\u304c\u5927\u304d\u306a\u6750\u6599\u3092\u9ad8\u5bc6\u5ea6\u306b\u5145\u586b\u3059\u308b\u5fc5\u8981\u304c\u3042\u308a\u307e\u3059\u3002\u96fb\u89e3\u8cea\u306f\u3053\u306e\u3088\u3046\u306a\u9ad8\u5bc6\u5ea6\u3067\u3059\u304d\u307e\u306e\u5c0f\u3055\u306a\u7a7a\u9593\u306b\u5165\u308a\u8fbc\u307f\u3001\u30b9\u30e0\u30fc\u30ba\u306b\u30a4\u30aa\u30f3\u3092\u53d7\u3051\u6e21\u3057\u3057\u306a\u3051\u308c\u3070\u306a\u308a\u307e\u305b\u3093\u3002\u305d\u306e\u74b0\u5883\u4e0b\u306b\u304a\u3044\u3066\u3001\u6eb6\u5a92\u304c\u56fa\u4f53\u3068\u3069\u306e\u3088\u3046\u306a\u76f8\u4e92\u4f5c\u7528\u3092\u6301\u3061\u3001\u30a4\u30aa\u30f3\u306e\u79fb\u52d5\u306b\u3069\u306e\u3088\u3046\u306a\u5f71\u97ff\u3092\u53ca\u307c\u3059\u304b\u3092\u77e5\u308b\u3053\u3068\u306f\u96fb\u6c60\u306e\u6027\u80fd\u3092\u5411\u4e0a\u3055\u305b\u308b\u4e0a\u3067\u91cd\u8981\u306a\u77e5\u898b\u3068\u306a\u308a\u307e\u3059\u3002<\/span><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" src=\"http:\/\/133.30.28.157\/wp-content\/uploads\/2022\/07\/pic0-298x300.jpg\" alt=\"\" width=\"298\" height=\"300\" class=\"size-medium wp-image-3805 aligncenter\" srcset=\"http:\/\/133.30.28.157\/wp-content\/uploads\/2022\/07\/pic0-298x300.jpg 298w, http:\/\/133.30.28.157\/wp-content\/uploads\/2022\/07\/pic0-150x150.jpg 150w, http:\/\/133.30.28.157\/wp-content\/uploads\/2022\/07\/pic0.jpg 600w\" sizes=\"(max-width: 298px) 100vw, 298px\" \/><\/p>\n<h4>\u7814\u7a76\u306e\u5185\u5bb9<\/h4>\n<p>\u3000\u4eca\u56de\u7528\u3044\u305f\u6eb6\u5a92\u306f\u30ea\u30c1\u30a6\u30e0\u96fb\u89e3\u8cea\u3092\u826f\u304f\u6eb6\u304b\u3059\u5206\u6975\u6027\u306e\u5f37\u3044\u70ad\u9178\u30d7\u30ed\u30d4\u30ec\u30f3 (PC) \u3068\u30a8\u30fc\u30c6\u30eb\u7d50\u5408\u3092\u6709\u3059\u308b\u4f4e\u7c98\u6027\u306a1\u30012\u30b8\u30e1\u30c8\u30b7\u30ad\u30a8\u30bf\u30f3 (DME) \u3068\u306e\u7d44\u307f\u5408\u308f\u305b\u306b\u3088\u308b\u6df7\u5408\u6eb6\u5a92\u3067\u3042\u308a\u3001\u672c\u6765\u9ad8\u3044\u96fb\u6c17\u4f1d\u5c0e\u6027\u3092\u793a\u3059\u3053\u3068\u304c\u53e4\u304f\u304b\u3089\u77e5\u3089\u308c\u3066\u3044\u307e\u3057\u305f\u3002\u3057\u304b\u3057\u306a\u304c\u3089\u3001\u91d1\u5c5e\u9178\u5316\u7269\u306e\u7c89\u4f53\u3068\u5171\u5b58\u3055\u305b\u308b\u3068 PC\u306bDME\u3092\u6dfb\u52a0\u3057\u3066\u3082\u96fb\u6c17\u4f1d\u5c0e\u7387\u306f\u5897\u52a0\u305b\u305a\u3001\u4f4e\u7c98\u6027\u6eb6\u5a92\u306e\u50cd\u304d\u304c\u5931\u308f\u308c\u3066\u3057\u307e\u3046\u3053\u3068\u304c\u308f\u304b\u3063\u3066\u3044\u307e\u3057\u305f\u3002<\/p>\n<p>\u3000\u9234\u6728\u30fb\u570b\u65b9\u306e\u4e21\u540d\u306f\u5de5\u5b66\u7814\u7a76\u79d1\u6c34\u7551\u7a63\u6559\u6388\u306e\u4e0b\u3001PC-DME\u306e\u6df7\u5408\u6eb6\u5a92\u3092\u7528\u3044\u305fLiClO4\u6eb6\u6db2\u3092\u30b7\u30ea\u30ab\u30ca\u30ce\u7c92\u5b50\u3068\u5171\u5b58\u3055\u305b\u3001\u30a4\u30aa\u30f3\u4f1d\u5c0e\u7387\u30fbNMR\u30fb\u30e9\u30de\u30f3\u5206\u5149\u30fb\u8d64\u5916\u5206\u5149\u306e\u6e2c\u5b9a\u3092\u884c\u3046\u3068\u3068\u3082\u306b\u3001\u6771\u5317\u5927\u5b66\u6559\u6388\u306b\u3088\u308a\u958b\u767a\u3055\u308c\u305f\u8868\u9762\u305a\u308a\u7c98\u6027\u6e2c\u5b9a\u6cd5\u3092\u7528\u3044\u308b\u3053\u3068\u306b\u3088\u3063\u3066\u3001\u672c\u6765\u7c98\u6027\u3092\u4f4e\u4e0b\u3055\u305b\u308b\u30a8\u30fc\u30c6\u30eb\u7cfb\u5206\u5b50\u304c\u56fa\u4f53\u8868\u9762\u306b\u51dd\u96c6\u3057\u3001\u6eb6\u5a92\u306e\u4e0d\u5747\u5316\u304c\u751f\u3058\u3001\u7c98\u6027\u3092\u4e0a\u3052\u3066\u3057\u307e\u3046\u3053\u3068\u3092\u898b\u3044\u51fa\u3057\u307e\u3057\u305f\u3002\u3053\u306e\u3053\u3068\u306f\u3001\u56fa\u4f53\u8868\u9762\u306b\u304a\u3051\u308b\u901a\u5e38\u306e\u30a4\u30aa\u30f3\u4f1d\u5c0e\u304c\u6291\u5236\u3055\u308c\u308b\u3053\u3068\u3092\u793a\u5506\u3057\u307e\u3059\u304c\u3001\u6bd4\u8f03\u7684\u9ad8\u6fc3\u5ea6\u306e\u96fb\u89e3\u6db2\u3092\u7528\u3044\u308b\u3053\u3068\u306b\u3088\u3063\u3066\u3001\u4e0d\u5747\u5316\u73fe\u8c61\u3092\u6291\u5236\u3059\u308b\u3053\u3068\u304c\u3067\u304d\u308b\u3053\u3068\u3082\u5b9f\u8a3c\u3057\u307e\u3057\u305f(\u56f31)\u3002<\/p>\n<p>&nbsp;<\/p>\n<div id=\"attachment_3801\" style=\"width: 710px\" class=\"wp-caption alignnone\"><img loading=\"lazy\" decoding=\"async\" aria-describedby=\"caption-attachment-3801\" src=\"http:\/\/133.30.28.157\/wp-content\/uploads\/2022\/07\/pic1.jpg\" alt=\"\" width=\"700\" height=\"155\" class=\"wp-image-3801 size-full\" srcset=\"http:\/\/133.30.28.157\/wp-content\/uploads\/2022\/07\/pic1.jpg 700w, http:\/\/133.30.28.157\/wp-content\/uploads\/2022\/07\/pic1-300x66.jpg 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><p id=\"caption-attachment-3801\" class=\"wp-caption-text\"><strong>\u56f31\u3000PC\u3068DME\u3068\u306e\u76f8\u5206\u96e2\u73fe\u8c61<\/strong> \u30ea\u30c1\u30a6\u30e0\u5869\u304c\u306a\u3044\u5834\u5408\u306b\u306f DME\u306f\u56fa\u4f53\u3068\u306e\u754c\u9762\u4ed8\u8fd1\u306b\u51dd\u96c6\u3057\u3001\u7c98\u6027\u304c\u975e\u5e38\u306b\u9ad8\u304f\u306a\u308b\u3053\u3068\u3092\u898b\u3044\u3060\u3057\u305f\u3002\u30ea\u30c1\u30a6\u30e0\u5869\u306e\u6fc3\u5ea6\u306e\u4e0a\u6607\u3068\u3068\u3082\u306b\u30a4\u30aa\u30f3\u306e\u6eb6\u5a92\u548c\u304c\u9032\u307f\u3001\u6eb6\u5a92\u306e\u4e0d\u5747\u5316\u306f\u8d77\u3053\u308a\u306b\u304f\u304f\u306a\u308b\u3002<\/p><\/div>\n<p>\u3000\u3053\u306e\u73fe\u8c61\u306f\u56fa\u4f53\u8868\u9762\u306bDME\u304c\u5438\u7740\u3057\u3084\u3059\u3044\u3068\u3044\u3046\u73fe\u8c61\u3092\u3001\u6838\u78c1\u6c17\u5171\u9cf4 (NMR) \u5206\u5149\u306b\u3088\u308b\u5b9a\u91cf\u5206\u6790\u306b\u3088\u308a\u898b\u3044\u3060\u3057\u305f\u3053\u3068\u3092\u304d\u3063\u304b\u3051\u306b\u3001\u591a\u304f\u306e\u7269\u6027\u6e2c\u5b9a\u3092\u7d4c\u3066\u660e\u3089\u304b\u306b\u3055\u308c\u3066\u304d\u307e\u3057\u305f\u3002\u56fa\u4f53\u3092\u6dfb\u52a0\u3059\u308b\u3068\u305d\u306e\u8868\u9762\u306b\u5438\u7740\u3057\u305fDME\u5206\u5b50\u306f\u305d\u306e\u52d5\u304d\u304c\u59a8\u3052\u3089\u308c\u3001NMR\u306e\u6e2c\u5b9a\u306b\u304a\u3044\u3066\u305d\u306e\u30d4\u30fc\u30af\u304c\u898b\u3089\u308c\u306a\u304f\u306a\u308a\u307e\u3059 (\u56f32)\u3002<\/p>\n<div id=\"attachment_3802\" style=\"width: 310px\" class=\"wp-caption alignright\"><img loading=\"lazy\" decoding=\"async\" aria-describedby=\"caption-attachment-3802\" src=\"http:\/\/133.30.28.157\/wp-content\/uploads\/2022\/07\/pic2-300x253.jpg\" alt=\"\" width=\"300\" height=\"253\" class=\"size-medium wp-image-3802\" srcset=\"http:\/\/133.30.28.157\/wp-content\/uploads\/2022\/07\/pic2-300x253.jpg 300w, http:\/\/133.30.28.157\/wp-content\/uploads\/2022\/07\/pic2.jpg 360w\" sizes=\"(max-width: 300px) 100vw, 300px\" \/><p id=\"caption-attachment-3802\" class=\"wp-caption-text\"><strong>\u56f32\u3000\u56fa\u4f53\u3068\u5171\u5b58\u3055\u305b\u305fPC-DME\u6df7\u5408\u6eb6\u5a92\u306eNMR\u30b9\u30da\u30af\u30c8\u30eb<\/strong><br \/>\n\u56fa\u4f53\u3068\u6df7\u5408\u3059\u308b\u3053\u3068\u306b\u3088\u308aPC\u306e\u30d4\u30fc\u30af(a\uff5ec)\u306f\u5168\u4f53\u7684\u306b\u5e45\u5e83\u306e\u30d4\u30fc\u30af\u306b\u306a\u308b\u304cDME\u306e\u30d4\u30fc\u30af(d,e)\u306f\u6db2\u76f890%\u4ee5\u4e0b\u3067\u306f\u307b\u3068\u3093\u3069\u898b\u3089\u308c\u306a\u304f\u306a\u308b\u3002<\/p><\/div>\n<p>\u3000\u3053\u306e\u3088\u3046\u306a\u73fe\u8c61\u304c\u751f\u3058\u308b\u3068\u4f4e\u7c98\u6027\u6eb6\u5a92\u3092\u52a0\u3048\u308b\u3053\u3068\u306b\u3088\u3063\u3066\u671f\u5f85\u3055\u308c\u308b\u30a4\u30aa\u30f3\u4f1d\u5c0e\u306e\u5411\u4e0a\u304c\u898b\u3089\u308c\u306a\u304f\u306a\u308b\u3060\u3051\u3067\u306a\u304f\u3001\u76f8\u5206\u96e2\u306b\u3088\u3063\u3066\u30a4\u30aa\u30f3\u304cPC\u5074\u306b\u6fc3\u7e2e\u3055\u308c\u3001\u30a4\u30aa\u30f3\u4f1d\u5c0e\u306e\u4f4e\u4e0b\u3092\u3082\u305f\u3089\u3059\u89e3\u96e2\u306e\u6291\u5236\u304c\u751f\u3058\u3066\u3057\u307e\u3044\u307e\u3059\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><span>\u3000\u3053\u306e\u73fe\u8c61\u3092\u3088\u308a\u7cbe\u5bc6\u306b\u89e3\u660e\u3057\u3001\u30a4\u30aa\u30f3\u4f1d\u5c0e\u3092\u3069\u306e\u3088\u3046\u306b\u5411\u4e0a\u3055\u305b\u308b\u304b\u3092\u691c\u8a0e\u3059\u308b\u305f\u3081\u3001\u8868\u9762\u305a\u308a\u7c98\u6027\u6e2c\u5b9a\u88c5\u7f6e\u306b\u3088\u308a\u56fa\u4f53\u8868\u9762\u4ed8\u8fd1\u3067\u306e\u6db2\u4f53\u306e\u7c98\u6027\u3092\u6e2c\u5b9a\u3057\u307e\u3057\u305f(\u56f33)\u3002\u3053\u306e\u88c5\u7f6e\u306f\u66f2\u9762\u304b\u3089\u306a\u308b\u8868\u9762\u3092\u3082\u3064\u77f3\u82f1\u3092\u5411\u304b\u3044\u5408\u308f\u305b\u306b\u914d\u7f6e\u3057\u3001\u305d\u306e\u3046\u3061\u7247\u65b9\u3092\u9ad8\u5468\u6ce2\u3067\u5171\u632f\u3055\u305b\u307e\u3059\u3002\u631f\u307e\u308c\u305f\u6db2\u4f53\u306e\u7c98\u5ea6\u304c\u9ad8\u304f\u306a\u308b\u3068\u3001\u6db2\u4f53\u306f\u56fa\u4f53\u3068\u3068\u3082\u306b\u632f\u52d5\u3092\u59cb\u3081\u3001\u3082\u3046\u7247\u65b9\u306e\u77f3\u82f1\u3068\u5171\u306b\u632f\u52d5\u3092\u59cb\u3081\u307e\u3059\u3002\u305d\u306e\u969b\u3001\u4e21\u65b9\u306e\u77f3\u82f1\u304c\u5171\u306b\u52d5\u304f\u3068\u5171\u9cf4\u632f\u52d5\u6570\u304c\u6975\u7aef\u306b\u5909\u5316\u3057\u307e\u3059\u3002\u3053\u306e\u88c5\u7f6e\u306f\u305d\u306e\u632f\u52d5\u306e\u5909\u5316\u3092\u5149\u5b66\u7684\u306b\u6349\u3048\u3001\u631f\u307e\u308c\u305f\u6db2\u4f53\u306e\u7c98\u6027\u3092\u6e2c\u5b9a\u3059\u308b\u88c5\u7f6e\u3068\u3057\u3066\u958b\u767a\u3055\u308c\u305f\u3082\u306e\u3067\u3059\u3002\u3053\u306e\u88c5\u7f6e\u3092\u7528\u3044\u308b\u3053\u3068\u306b\u3088\u308a\u3001\u6570nm\u306e\u3059\u304d\u307e\u306b\u631f\u307e\u308c\u305f\u6db2\u4f53\u304c2\u76f8\u306b\u5206\u304b\u308c\u3001DME\u304c\u8868\u9762\u306b\u5b58\u5728\u3059\u308b\u3068\u5358\u4e00\u6eb6\u5a92\u7cfb\u306e\u5834\u5408\u3088\u308a\u6975\u3081\u3066\u9577\u8ddd\u96e2\u307e\u3067\u632f\u52d5\u304c\u4f1d\u642c\u3059\u308b\u3053\u3068\u304c\u308f\u304b\u308a\u307e\u3057\u305f (\u56f34)\u3002<\/span><\/p>\n<p><div id=\"attachment_3803\" style=\"width: 610px\" class=\"wp-caption alignnone\"><img loading=\"lazy\" decoding=\"async\" aria-describedby=\"caption-attachment-3803\" src=\"http:\/\/133.30.28.157\/wp-content\/uploads\/2022\/07\/pic3.jpg\" alt=\"\" width=\"600\" height=\"351\" class=\"wp-image-3803 size-full\" srcset=\"http:\/\/133.30.28.157\/wp-content\/uploads\/2022\/07\/pic3.jpg 600w, http:\/\/133.30.28.157\/wp-content\/uploads\/2022\/07\/pic3-300x176.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><p id=\"caption-attachment-3803\" class=\"wp-caption-text\"><strong>\u56f33\u3000\u305a\u308a\u7c98\u6027\u6e2c\u5b9a\u88c5\u7f6e<\/strong><br \/>\n\u77f3\u82f1\u306b\u631f\u307e\u308c\u305f\u6db2\u4f53\u306e\u9593\u9694\u306f\u6570nm\u307e\u3067\u8fd1\u3065\u3044\u3066\u3044\u308b\u3053\u3068\u3092\u5149\u306e\u5e72\u6e09\u3067\u6e2c\u5b9a\u3059\u308b\u3002<\/p><\/div> <div id=\"attachment_3804\" style=\"width: 710px\" class=\"wp-caption alignnone\"><img loading=\"lazy\" decoding=\"async\" aria-describedby=\"caption-attachment-3804\" src=\"http:\/\/133.30.28.157\/wp-content\/uploads\/2022\/07\/pic4.jpg\" alt=\"\" width=\"700\" height=\"300\" class=\"wp-image-3804 size-full\" srcset=\"http:\/\/133.30.28.157\/wp-content\/uploads\/2022\/07\/pic4.jpg 700w, http:\/\/133.30.28.157\/wp-content\/uploads\/2022\/07\/pic4-300x129.jpg 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><p id=\"caption-attachment-3804\" class=\"wp-caption-text\"><strong>\u56f34\u3000\u305a\u308a\u7c98\u6027\u6e2c\u5b9a\u88c5\u7f6e\u3067\u3048\u3089\u308c\u305f\u632f\u52d5\u306e\u4f1d\u642c\u3092\u793a\u3059\u30b0\u30e9\u30d5\uff08\u5de6\uff09\u3068\u305a\u308a\u7c98\u5ea6\u3068\u77f3\u82f1\u9593\u8ddd\u96e2\u3068\u306e\u95a2\u4fc2<\/strong><br \/>\n\u3053\u306e\u7d50\u679c\u3067\u306f\u77f3\u82f1\u306e\u9593\u9694\u3092\u7d0410nm\u3068\u3057\u305f\u3068\u304d\u3001\u5171\u9cf4\u632f\u52d5\u6570\u304c200\u2192350rad\/s\u3068\u6975\u7aef\u306b\u5897\u52a0\u3057\u3001\u76f4\u63a5\u63a5\u89e6\u3057\u306a\u304f\u3066\u3082\u77f3\u82f1\u9593\u3067\u306e\u632f\u52d5\u304c\u4f1d\u642c\u3057\u3066\u3044\u308b\u3053\u3068\u304b\u3089\u9593\u306e\u6db2\u4f53\u306e\u7c98\u6027\u304c\u5897\u52a0\u3057\u3066\u3044\u308b\u3053\u3068\u304c\u308f\u304b\u308b\u3002PC\u3068DME\u3068\u306e\u6df7\u5408\u6eb6\u5a92\u3067\u306f\u3053\u306e\u632f\u52d5\u306e\u4f1d\u642c\u304c60 nm\u304b\u3089\u8d77\u304d\u3066\u304a\u308a\u3001\u5358\u4e00\u6eb6\u5a92\u3068\u306f\u5168\u304f\u7570\u306a\u308b\u69cb\u9020\u3092\u3068\u308b\u3053\u3068\u304c\u793a\u5506\u3055\u308c\u308b\u3002<\/p><\/div><\/p>\n<p>\u3000\u3053\u306e\u73fe\u8c61\u306f\u7279\u306bPC-DME\u6df7\u5408\u6eb6\u5a92\u7cfb\u3067\u6975\u7aef\u306b\u793a\u3055\u308c\u3001\u5f93\u6765\u7d44\u6210\u3092\u5236\u5fa1\u3059\u308c\u3070\u3088\u3044\u3068\u3055\u308c\u3066\u304d\u305f\u4e8c\u5143\u7cfb\u6eb6\u5a92\u306e\u50cd\u304d\u304c\u56fa\u4f53\u8fd1\u508d\u3067\u5927\u304d\u304f\u5909\u5316\u3059\u308b\u3053\u3068\u304c\u793a\u3055\u308c\u308b\u3068\u3044\u3046\u8208\u5473\u6df1\u3044\u7d50\u679c\u304c\u5f97\u3089\u308c\u307e\u3057\u305f\u3002\u4e00\u65b9\u3001\u4e00\u822c\u7684\u306b\u96fb\u6c60\u3067\u7528\u3044\u3089\u308c\u308b\u30ea\u30c1\u30a6\u30e0\u96fb\u89e3\u6db2\u306e\u6fc3\u5ea6 (\u7d041 mol\/L,\u7d0410%) \u3088\u308a\u3082\u9ad8\u304f\u306a\u308a\u30012\uff5e3 mol L-1 (\u7d0420-30%) \u306b\u306a\u308b\u3068\u3001\u4e0d\u5747\u4e00\u306a\u69cb\u9020\u3092\u3068\u308bDME\u304c\u30ea\u30c1\u30a6\u30e0\u30a4\u30aa\u30f3\u3068\u5b89\u5b9a\u306a\u6eb6\u6db2\u69cb\u9020\u3092\u5f62\u6210\u3059\u308b\u3053\u3068\u3082\u308f\u304b\u308a\u307e\u3057\u305f\u3002\u3053\u306e\u3053\u3068\u304b\u3089\u6fc3\u539a\u7cfb\u6eb6\u6db2\u306e\u5229\u7528\u306b\u304a\u3051\u308b\u30a4\u30aa\u30f3\u4f1d\u5c0e\u7387\u306e\u5411\u4e0a\u304c\u8a8d\u3081\u3089\u308c\u308b\u3053\u3068\u3082\u308f\u304b\u308a\u307e\u3057\u305f\u3002\u3055\u3089\u306b\u3053\u306e\u73fe\u8c61\u306b\u304a\u3051\u308b\u56fa\u4f53\uff0d\u30a4\u30aa\u30f3\u9593\u3001\u30a4\u30aa\u30f3\uff0d\u6eb6\u5a92\u9593\u306e\u76f8\u4e92\u4f5c\u7528\u3092\u30e9\u30de\u30f3\u5206\u5149\u5206\u6790\u306b\u3088\u308a\u6e2c\u5b9a\u3057\u3066\u304a\u308a\u3001\u3055\u307e\u3056\u307e\u306a\u6db2\u4f53\u4e2d\u306e\u69cb\u9020\u5909\u5316\u3068\u56fa\u4f53\u8868\u9762\u306b\u304a\u3051\u308b\u30a4\u30aa\u30f3\u4f1d\u5c0e\u3068\u306e\u9593\u3067\u76f8\u95a2\u304c\u3042\u308b\u3053\u3068\u3092\u898b\u3044\u3060\u3057\u3066\u3044\u307e\u3059\u3002<\/p>\n<p>\u3000\u3053\u306e\u56fa\u4f53\u3068\u6db2\u4f53\u3068\u306e\u754c\u9762\u306b\u304a\u3051\u308b\u7279\u7570\u306a\u73fe\u8c61\u306f\u3088\u308a\u9ad8\u51fa\u529b\u30fb\u9ad8\u5bb9\u91cf\u306a\u96fb\u6c60\u3092\u958b\u767a\u3059\u308b\u4e0a\u3067\u3001\u96fb\u6975\u6750\u6599\u306e\u754c\u9762\u5236\u5fa1\u304c\u91cd\u8981\u306a\u5f79\u5272\u3092\u3082\u3064\u3053\u3068\u3092\u793a\u3059\u3082\u306e\u3068\u3057\u3066\u3001\u9ad8\u3044\u95a2\u5fc3\u3092\u547c\u3093\u3067\u3044\u307e\u3059\u3002\u672c\u7814\u7a76\u3092\u884c\u3063\u305f\u9234\u6728\u306f\u95a2\u9023\u3059\u308b\u7814\u7a76\u3067\u516c\u76ca\u793e\u56e3\u6cd5\u4eba\u96fb\u6c17\u5316\u5b66\u4f1a\u304b\u30892021\u5e74\u30012022\u5e74\u306e2\u5ea6\u306b\u6e21\u3063\u3066\u5b66\u751f\u8b1b\u6f14\u5968\u52b1\u8cde\u3092\u53d7\u8cde\u3057\u3066\u3044\u308b\u4ed6\u3001\u672c\u5b66\u6b21\u4e16\u4ee3\u7814\u7a76\u8005\u6311\u6226\u7684\u7814\u7a76\u30d7\u30ed\u30b0\u30e9\u30e0\u306e\u4e0b\u3001\u4f01\u696d\u3068\u306e\u5171\u540c\u7814\u7a76\u306b\u7a4d\u6975\u7684\u306b\u53c2\u753b\u3057\u3066\u304a\u308a\u3001\u672c\u7814\u7a76\u3082\u305d\u306e\u6210\u679c\u306b\u5927\u304d\u304f\u8ca2\u732e\u3059\u308b\u3053\u3068\u306b\u306a\u308a\u307e\u3057\u305f\u3002<\/p>\n<h4>\u4eca\u5f8c\u306e\u5c55\u958b<\/h4>\n<p><span>\u3000\u795e\u6238\u5927\u5b66\u5927\u5b66\u9662\u5de5\u5b66\u7814\u7a76\u79d1\u5fdc\u7528\u5316\u5b66\u5c02\u653b\u7121\u6a5f\u7269\u8cea\u5275\u6210\u5316\u5b66\u7814\u7a76\u5ba4\u3067\u306f\u6c34\u7551\u7a63\u6559\u6388\u306e\u30e9\u30a4\u30d5\u30ef\u30fc\u30af\u3067\u3042\u308b\u754c\u9762\u96fb\u6c17\u5316\u5b66\u3092\u30d9\u30fc\u30b9\u306b\u96fb\u6c17\u5316\u5b66\u30c7\u30d0\u30a4\u30b9\u306b\u304a\u3051\u308b\u69d8\u3005\u306a\u7279\u7570\u7684\u73fe\u8c61\u306e\u89e3\u660e\u3092\u9032\u3081\u3066\u3044\u307e\u3059\u3002\u672c\u6210\u679c\u306f\u96fb\u6c60\u6750\u6599\u3060\u3051\u3067\u306a\u304f\u3001\u69d8\u3005\u306a\u56fa\u6db2\u754c\u9762\u3092\u6709\u3059\u308b\u6750\u6599\u306e\u8a55\u4fa1\u6cd5\u306b\u3082\u95a2\u4fc2\u3057\u3066\u304a\u308a\u3001\u96fb\u6c60\u6750\u6599\u3001\u91d1\u5c5e\u8150\u98df\u3001\u30bb\u30e9\u30df\u30c3\u30af\u30b9\u3092\u7528\u3044\u305f\u5149\u96fb\u6c17\u5316\u5b66\u6750\u6599\u7b49\u3001\u591a\u69d8\u306a\u754c\u9762\u3092\u7528\u3044\u305f\u30a8\u30cd\u30eb\u30ae\u30fc\u5909\u63db\u6750\u6599\u306e\u5275\u6210\u306b\u53d6\u308a\u7d44\u3093\u3067\u3044\u304d\u307e\u3059\u3002<\/span><\/p>\n<p>&nbsp;<\/p>\n<h5>\u8ad6\u6587\u60c5\u5831<\/h5>\n<p>\u30bf\u30a4\u30c8\u30eb\uff1a\u201c<a href=\"https:\/\/doi.org\/10.1021\/acs.jpcc.2c02980\">Disproportionation Phenomenon at the Silica Interface of Propylene Carbonate\u20131,2-Dimethoxyethane Binary Solvent containing Lithium Perchlorate<\/a>\u201d<\/p>\n<p>DOI\uff1a10.1021\/acs.jpcc.2c02980<\/p>\n<p>\u8457\u8005\uff1aYoshimasa Suzuki, Nobuaki Kunikata, Motohiro Kasuya, Hideshi Maki, Masaki Matsui, Kazue Kurihara, and Minoru Mizuhata<\/p>\n<p>\u63b2\u8f09\u8a8c\uff1a<i>Journal of Physical Chemistry C<\/i><\/p>\n<h5>\u95a2\u9023\u30ea\u30f3\u30af<\/h5>\n<p>\u795e\u6238\u5927\u5b66\u5927\u5b66\u9662\u5de5\u5b66\u7814\u7a76\u79d1\u5fdc\u7528\u5316\u5b66\u5c02\u653b\u30db\u30fc\u30e0\u30da\u30fc\u30b8\uff1a<a href=\"http:\/\/www.cx.kobe-u.ac.jp\/\" target=\"_blank\" rel=\"noopener\">http:\/\/www.cx.kobe-u.ac.jp\/<\/a><\/p>\n<p>\u795e\u6238\u5927\u5b66\u516c\u5f0f\u30db\u30fc\u30e0\u30da\u30fc\u30b8\u3000\u7814\u7a76\u30cb\u30e5\u30fc\u30b9\u30b5\u30a4\u30c8\uff1a<a href=\"https:\/\/www.kobe-u.ac.jp\/research_at_kobe\/NEWS\/news\/2022_07_27_01.html\" target=\"_blank\" rel=\"noopener\">https:\/\/www.kobe-u.ac.jp\/research_at_kobe\/NEWS\/news\/2022_07_27_01.html<\/a><\/p>\n<p>\u63b2\u8f09\u8a8c\uff08<i>Journal of Physical Chemistry C<\/i>\uff09\u516c\u5f0fTwitter\uff08\u4eca\u56de\u306e\u8ad6\u6587\u304c\u7d39\u4ecb\u3055\u308c\u3066\u3044\u307e\u3059\uff09\uff1a<\/p>\n<p><a href=\"https:\/\/twitter.com\/JPhysChem\/status\/1551993253347708931\" target=\"_blank\" rel=\"noopener\">https:\/\/twitter.com\/JPhysChem\/status\/1551993253347708931<\/a><\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u6982\u8981 &nbsp; \u3000\u795e\u6238\u5927\u5b66\u5927\u5b66\u9662\u5de5\u5b66\u7814\u7a76\u79d1\u5fdc\u7528\u5316\u5b66\u5c02\u653b\u306e\u5927\u5b66\u9662\u751f \u9234\u6728\u826f\u5c06\u3001\u570b\u65b9\u4f38\u4eae (\u73fe\u30fb\u5bcc\u5c71\u770c\u7523\u696d\u6280\u8853\u7814\u7a76\u958b\u767a\u30bb\u30f3\u30bf\u30fc) \u3089\u306f\u3001\u30ca\u30ce\u7a7a\u9593\u306b\u5b58\u5728\u3059\u308b\u96fb\u6c60\u7528\u96fb\u89e3\u6db2\u306b\u7528\u3044\u3089\u308c\u308b\u4e8c\u5143\u7cfb\u975e\u6c34\u6eb6\u5a92\u306b\u304a\u3044\u3066\u6eb6\u5a92\u304c\u4e0d\u5747\u5316\u3092\u304a\u3053\u3059 [&hellip;]<\/p>\n","protected":false},"author":11,"featured_media":3828,"parent":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"footnotes":"","_links_to":"","_links_to_target":""},"tax_div":[59],"acf":[],"_links":{"self":[{"href":"http:\/\/133.30.28.157\/wp-json\/wp\/v2\/achievement\/3800"}],"collection":[{"href":"http:\/\/133.30.28.157\/wp-json\/wp\/v2\/achievement"}],"about":[{"href":"http:\/\/133.30.28.157\/wp-json\/wp\/v2\/types\/achievement"}],"author":[{"embeddable":true,"href":"http:\/\/133.30.28.157\/wp-json\/wp\/v2\/users\/11"}],"replies":[{"embeddable":true,"href":"http:\/\/133.30.28.157\/wp-json\/wp\/v2\/comments?post=3800"}],"version-history":[{"count":21,"href":"http:\/\/133.30.28.157\/wp-json\/wp\/v2\/achievement\/3800\/revisions"}],"predecessor-version":[{"id":3829,"href":"http:\/\/133.30.28.157\/wp-json\/wp\/v2\/achievement\/3800\/revisions\/3829"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/133.30.28.157\/wp-json\/wp\/v2\/media\/3828"}],"wp:attachment":[{"href":"http:\/\/133.30.28.157\/wp-json\/wp\/v2\/media?parent=3800"}],"wp:term":[{"taxonomy":"tax_div","embeddable":true,"href":"http:\/\/133.30.28.157\/wp-json\/wp\/v2\/tax_div?post=3800"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}